D28000

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D28000

Aldrich

 

Diazald®

99%

Synonym:N-Methyl-N-(p-tolylsulfonyl)nitrosamide, N-Methyl-N-nitroso-p-toluenesulfonamide, N-Nitroso-N-methyl-p-toluenesulfonamide, N-Nitroso-p-toluenesulfomethylamide, p-Tolylsulfomethylnitrosamide, Diazomethane precursor
CAS Number:80-11-5
Linear Formula:CH3C6H4SO2N(CH3)NO
Molecular Weight:214.24
Beilstein Registry Number:2214345
EC Number:201-252-6
MDL number:MFCD00002050
PubChem Substance ID:24893716

Description

Frequently Asked QuestionsLive Chat and Frequently Asked Questions are available for this Product.
ApplicationNitrosylating agent for transition metal complexes,1 amines,2 and carbanions,3 as well as a precursor to diazomethane.4
Packaging25 g in poly btl
Legal InformationDiazald is a registered trademark of Sigma-Aldrich Biotechnology LP and Sigma-Aldrich Co.

Properties

assay99%
mp61-62 °C(lit.)

Safety

Hazard CodesE,Xi
Risk Statements2-36/37/38-43
Safety Statements15-26-35-36/37
RIDADRUN 3234 4.1/PG 2
WGK Germany2
RTECSXT5950000

Related Products

Related productZ547867, Inner tube for System 45® MNNG diazomethane generator
 Z108510, Macro Diazald® kits
 Z411736, Aldrich® diazomethane-generator with System 45® compatible connection
 Z419761, Diazald® set with System 45® compatible connections
 Z100250, Diazald® kit with Clear-Seal® joints
 Z203076, Macro Diazald® kits

References

Cited Reference1. Organometallics 12, 1029, (1993)
 2. J. Chem. Soc., Perkin Trans. II, 29, (1993)
 3. J. Chem. Soc., Perkin Trans. II, 1233, (1993)
 4. J. Chromatogr. Sci. 29, 8, (1991)
MerckMerck 13,9621
BeilsteinBeil. 11,IV,478
FieserFieser 1,191 / Fieser 2,102
referenceAldrich MSDS 1, 572:C / Corp MSDS 1 (1), 1062:B / FT-IR 2 (2), 3292:B / FT-IR 1 (2), 531:D / FT-NMR 1 (2), 1635:A / IR-Spectra (3), 1175:G / IR-Spectra (2), 1024:C / NMR-Reference 2 (2), 851:A / RegBook 1 (2), 2241:E / Sax 6, 2601 / Sigma FT-IR 1 (2), 744:D / Structure Index 1, 351:C:9